Chemical Kinetics mein rate laws, order of reaction aur Arrhenius equation aate hain. Yahan aapko is chapter ke sabse important formulas aur quick revision points free milte hain — NCERT/CBSE syllabus ke hisaab se, boards aur JEE/NEET dono ke liye.
Important Formulas & Concepts — Chemical Kinetics
- Rate = k[A]^x[B]^y; order = x + y
- Zero order: [A] = [A]₀ − kt; t½ = [A]₀/2k
- First order: k = (2.303/t)·log([A]₀/[A])
- First order t½ = 0.693/k (concentration-independent)
- Arrhenius: k = A·e^(−Ea/RT)
- log(k₂/k₁) = (Ea/2.303R)(1/T₁ − 1/T₂)
- Rate temperature coefficient ≈ 2-3 per 10°C
- Units of k: first order s⁻¹, zero order mol L⁻¹s⁻¹
Quick Revision Points
- Order experimental hai, molecularity theoretical
- First order ka t½ concentration par depend nahi karta — pehchan hai
- Catalyst Ea ghatata hai, ΔH nahi badalta
- log k vs 1/T graph ka slope = −Ea/2.303R
- Pseudo first order: ester hydrolysis (water excess)
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FAQ
Order determine kaise karte hain?
Initial rate method + integrated rate law — dono ke solved examples PDF mein hain.
Graphs kaunse important hain?
[A] vs t, log[A] vs t, k vs 1/T — teeno ke shapes PDF ke visual sheet mein hain.
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